| Property | Allanal 24‑10‑30 | Aviana Violet | Nicole Aria | |---|---|---|---| | λ_max (UV‑Vis) | 380 nm, 540 nm | 395 nm, 560 nm | 365 nm, 515 nm | | ε (M⁻¹ cm⁻¹) | 1.2 × 10⁴, 8.5 × 10³ | 1.0 × 10⁴, 9.0 × 10³ | 9.5 × 10³, 7.8 × 10³ | | λ_em (Fluorescence) | 500 nm (peak) | 530 nm | 485 nm | | Quantum yield (Φ) | 0.31 | 0.28 | 0.22 |
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Allanal 24‑10‑30 is a newly synthesised organic chromophore designed to mimic the structural‑colour mechanisms found in avian plumage. In this study we report the full physicochemical characterisation of Allanal 24‑10‑30, its integration into model feather‑like matrices, and a comparative analysis of the resulting optical properties with those of natural avian pigments. The compound was prepared via a three‑step convergent synthesis, yielding 78 % overall. High‑resolution mass spectrometry (HR‑MS) and ^1H/^13C NMR confirmed the intended structure. UV‑Vis absorption peaks at 380 nm and 540 nm, while fluorescence emission exhibited a Stokes shift of 120 nm, matching the spectral signatures of iridescent feathers observed in several passerine species. When incorporated into a keratin‑based scaffold, Allanal 24‑10‑30 generated a hue that closely approximates the vivid violet of the Cyanocitta cristata (blue jay) and the deep mauve of the Ptilonorhynchus violaceus (violet‑crowned woodswallow). Computational TD‑DFT calculations rationalise the observed bathochromic shift in terms of extended π‑conjugation and intramolecular charge transfer. Our findings suggest that Allanal 24‑10‑30 can serve as a versatile, bio‑compatible colourant for biomimetic applications and offers a new platform for probing the molecular basis of avian coloration. | Property | Allanal 24‑10‑30 | Aviana Violet
| Technique | Instrument | Parameters | |---|---|---| | UV‑Vis | Cary 60 (Agilent) | 200‑800 nm, 1 nm step | | Fluorescence | Fluorolog‑3 (Horiba) | Excitation 380 nm, emission 400‑700 nm | | FT‑IR | Nicolet iS50 (Thermo) | 4000‑400 cm⁻¹ | | Raman | Renishaw inVia | 785 nm laser, 10 s integration | In this study we report the full physicochemical
As they opened the book, they discovered that it was a diary written by a reclusive author, known only by the pseudonym "Allanal." The entries detailed a series of cryptic events and encounters that seemed to be connected to the numbers 24 and 30.